The most common CC/BCC mistake
Putting a large recipient list in the "To" or "Cc" field for a mass email exposes everyone's address to everyone else on the list -- a privacy slip that's easily avoided by using Bcc instead whenever recipients don't need to know who else received the message.
Reply All behaves differently depending on where someone was added
A person in the To or Cc field is included if someone hits Reply All, but a Bcc recipient never receives replies through Reply All -- since Bcc is meant to be invisible, and other recipients literally don't know that address exists to reply to.
Frequently Asked Questions
Can a Cc'd recipient see who was Bcc'd?
No -- Bcc addresses are hidden from every other recipient on the email, including those in the To and Cc fields, not just from each other.
Is it rude to Bcc someone into an ongoing conversation?
It can come across that way if discovered, since the other participants have no idea a new person is silently reading the thread -- for that reason, it's often better to loop someone in openly with Cc, or forward the thread to them directly instead.